Search results for "Emission spectrum"
showing 10 items of 293 documents
Long-term evolution of luminescent properties in CdI2 crystals
2016
Fresh and aged melt-grown or gas-phase grown CdI2 crystals are studied by means of low-temperature photoluminescence spectroscopy. Noticeable transformations of emission spectra are observed after long-term aging. The formation of nanostructures containing cadmium oxide and cadmium hydroxide as well as the changes in local surrounding of iodine atoms and the possible growth of polytypic modifications of CdI2 are taken into account when considering the diversity of optical spectra.
Correlations between density distributions, optical spectra, and ion species in a hydrogen plasma (invited)
2016
An experimental study of plasma distributions in a 2.45 GHz hydrogen discharge operated at 100 Hz repetition rate is presented. Ultrafast photography, time integrated visible light emission spectra, time resolved Balmer-alpha emission, time resolved Fulcher Band emission, ion species mass spectra, and time resolved ion species fraction measurements have been implemented as diagnostic tools in a broad range of plasma conditions. Results of plasma distributions and optical emissions correlated with H + , H + 2 , and H + 3 ion currents by using a Wien filter system with optical observation capability are reported. The magnetic field distribution and strength is found as the most critical facto…
Study of the thermochromic phase transition in CuMo1−xWxO4 solid solutions at the W L3-edge by resonant X-ray emission spectroscopy
2021
Abstract Polycrystalline CuMo 1 − x W x O 4 solid solutions were studied by resonant X-ray emission spectroscopy (RXES) at the W L 3 -edge to follow a variation of the tungsten local atomic and electronic structures across thermochromic phase transition as a function of sample composition and temperature. The experimental results were interpreted using ab initio calculations. The crystal-field splitting parameter Δ for the 5d(W)-states was obtained from the analysis of the RXES plane and was used to evaluate the coordination of tungsten atoms. Temperature-dependent RXES measurements were successfully employed to determine the hysteretic behaviour of the structural phase transition between t…
Fourier-transform spectroscopy and deperturbation analysis of the spin-orbit coupled A(1)Σ(+) and b(3)Π states of KRb.
2016
Fourier-transform A(1)Σ(+) - b(3)Π → X(1)Σ(+) laser-induced fluorescence spectra were recorded for the natural mixture of (39,41)K(85,87)Rb isotopologues produced in a heatpipe oven. Overall 4200 rovibronic term values of the spin-orbit coupled A(1)Σ(+) and b(3)Π states were determined with an uncertainty of about 0.01 cm(-1) in the energy range [10 850, 14 200] cm(-1) covering rotational quantum numbers J' ∈ [3, 280]. Direct deperturbation analysis of the A ∼ b complex performed within the framework of the A(1)Σ(+) ∼ b(3)ΠΩ=0,1,2 coupled-channel approach reproduced experimental data with a standard deviation of 0.004 cm(-1). Initial parameters of the internuclear potentials and spin-orbit …
Spiro-fused bis-hexa-peri-hexabenzocoronene.
2018
A spiro-fused hexa-peri-hexabenzocoronene dimer was synthesized, and its physicochemical properties were studied by UV-Vis absorption and emission spectroscopy as well as cyclic voltammetry. Chemical oxidation of SB-HBC afforded its radical cation and dication derivatives, which could be reversibly reduced to the neutral state.
Effect of quaternary ammonium salts on spectral properties of zinc octacarboxyphthalocyanine
2020
Abstract The paper presents results of the research on the influence of quaternary ammonium salts on UV–vis absorption and emission spectra of zinc octacarboxyphthalocyanine (ZnPcOC). Quaternary ammonium salts which show biological activity play a crucial role. In ZnPcOC solutions with a proper concentration of tetrabutylammonium salts (TBAX), a strong bathochromic shift band (λmax = 760 nm – “R” band) showing red fluorescence appears in time. The presence of tetrabutylammonium salt causes pH increase and, consequently, a gradual dissociation of carboxyl groups in ZnPcOC molecule. It seems that –COO— anions present in the ZnPcOC complex can interact with tetraalkylammonium cations, causing …
The photochemistry of mono- and dinuclear cyclometalated bis(tridentate)ruthenium(ii) complexes: dual excited state deactivation and dual emission
2016
The synthesis and characterization of a series of weakly emissive mononuclear cyclometalated [Ru(dpb-R)(tpy)](+) complexes with functional groups R of varying electron-donating characters at the dpb ligand are described (dpbH = 1,3-di(2-pyridyl)benzene, tpy = 2,2';6',2''-terpyridine, 1(+): R = NHCOMe, 2(+): R = NH2, 3(+): R = COOEt, 4(+): R = COOH). Steady-state emission spectroscopy in the temperature range between 298 K and 77 K revealed a previously unrecognized excited state deactivation pathway via low-lying triplet ligand-to-ligand ((3)LL'CT) charge transfer states in addition to the well-known pathway via(3)MC states. Thermal activation barriers for depopulation of the emissive metal…
Remote Control by π-Conjugation of the Emissive Properties of Fischer Carbene-BODIPY Dyads.
2016
The synthesis, structure, and complete characterization of mono- and bimetallic dyads joining Fischer carbene complexes and BODIPY chromophores are reported. In these organometallic species, the Fischer carbene complex is attached to the BODIPY moiety through a p-aminophenyl group linked at the C8 carbon atom of the BODIPY core. The photophysical properties, namely the corresponding UV/vis absorption and emission spectra of these new metal-carbene complexes, are analyzed and discussed. It is found that whereas the absorption of the considered dyads strongly resembles that of the parent 4-anilinyl-substituted BODIPY, the fluorescence emission is significantly reduced in these species, very l…
IGR J17329-2731: The birth of a symbiotic X-ray binary
2018
We report on the results of the multiwavelength campaign carried out after the discovery of the INTEGRAL transient IGR J17329-2731. The optical data collected with the SOAR telescope allowed us to identify the donor star in this system as a late M giant at a distance of 2.7$^{+3.4}_{-1.2}$ kpc. The data collected quasi-simultaneously with XMM-Newton and NuSTAR showed the presence of a modulation with a period of 6680$\pm$3 s in the X-ray light curves of the source. This unveils that the compact object hosted in this system is a slowly rotating neutron star. The broadband X-ray spectrum showed the presence of a strong absorption ($\gg$10$^{23}$ cm$^{-2}$) and prominent emission lines at 6.4 …
ARES. III. Unveiling the Two Faces of KELT-7 b with HST WFC3
2020
We present the analysis of the hot-Jupiter KELT-7b using transmission and emission spectroscopy from the Hubble Space Telescope (HST), both taken with the Wide Field Camera 3 (WFC3). Our study uncovers a rich transmission spectrum which is consistent with a cloud-free atmosphere and suggests the presence of H2O and H-. In contrast, the extracted emission spectrum does not contain strong absorption features and, although it is not consistent with a simple blackbody, it can be explained by a varying temperature-pressure profile, collision induced absorption (CIA) and H-. KELT-7 b had also been studied with other space-based instruments and we explore the effects of introducing these additiona…